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Home - News - Applications and Pros and Cons of Tert-Butyl Perbenzoate (TBPB)

Applications and Pros and Cons of Tert-Butyl Perbenzoate (TBPB)

July 31, 2023

Tert-Butyl Perbenzoate (TBPB) is a chemical compound that is widely used in the chemical industry as a radical initiator. It is a colorless liquid with a faint odor and is highly reactive. TBPB is a versatile compound that finds its use in many applications, including polymerization, cross-linking, and curing.


TBPB is composed of two main parts, the tert-butyl group, and the perbenzoate group. The tert-butyl group is a branched alkyl group that contains four carbon atoms. The perbenzoate group is an ester group that contains a benzene ring and a carboxylic acid group. The perbenzoate group is responsible for the radical initiation of TBPB.


One of the primary uses of TBPB is as a radical initiator in polymerization reactions. TBPB is used as a free radical initiator in the production of polymers such as polyethylene, polypropylene, and polystyrene. In these reactions, TBPB undergoes homolytic cleavage, producing two radicals that initiate the polymerization process.


TBPB is also used as a cross-linking agent in the production of cross-linked polymers. Cross-linked polymers are materials that have been chemically bonded together to form a three-dimensional network. This network gives the material its unique properties such as increased strength, rigidity, and resistance to heat and chemicals. TBPB is used as a cross-linking agent in the production of materials such as rubber, silicone, and epoxy resins.


Another important use of TBPB is as a curing agent. Curing is the process of hardening or solidifying a material by chemical reaction. TBPB is used as a curing agent in the production of coatings, adhesives, and sealants. In these applications, TBPB reacts with other compounds to form a cross-linked network that provides the material with its final properties.
TBPB is also used in the production of photopolymers. Photopolymers are materials that change their properties when exposed to light. TBPB is used in the production of photopolymers as a photoinitiator. When exposed to light, TBPB undergoes homolytic cleavage, producing two radicals that initiate the polymerization process.


TBPB has many advantages over other radical initiators. It has a low decomposition temperature and a high reactivity rate, making it an excellent choice for many applications. It also has a long shelf life and can be stored for extended periods without decomposing.


However, TBPB also has some disadvantages. It can be hazardous if not handled properly and can cause skin irritation and respiratory problems if inhaled. It is also highly flammable and should be stored and handled with care.


In conclusion, Tert-Butyl Perbenzoate (TBPB) is a versatile compound that finds its use in many applications in the chemical industry. It is used as a radical initiator in polymerization reactions, a cross-linking agent in the production of cross-linked polymers, a curing agent in the production of coatings, adhesives, and sealants, and as a photoinitiator in the production of photopolymers. Despite its advantages, TBPB should be handled with care due to its hazardous nature.