Provide Sample Tert-butanol Potassium Tert-butoxide 865-47-4 With Certification
Name: potassium tert-butoxide
CAS: 865-47-4
Acidity coefficient (pKa): pK1:18 (25°C)
Color: Whitetooff-white
Stability: Stable, butreacts violentlywithwaterandacids,possibly leadingtofire.Incompatiblewithwater,acids,halogenatedhydrocarbons,alcohols,strongoxidizingagents,ketones,carbondioxide.InChIKey:LPNYRYFBWFDTMA-UHFFFAOYSA-N
Water Solubility: REACTS Sensitivity: MoistureSensitive
Hydrolysis Sensitivity: 7: reactsslowlywithmoisture/water
Solubility:Solubleinhexane,toluene,diethyletherandterahydrofuran.
Product Parameters
Item | Value |
WGK Germany | 1 |
F | 10-21 |
Auto-ignition temperature | 483 °℃ |
Hazard Note | Flammable solid/Corrosive |
TSCA | Yes |
HazardClass | 8 |
PackingGroup | | |
Customs code | 29051900 |
Potassium tert-butoxide, an organic strong base, is an important organic base, and its basicity is greater than that of potassium hydroxide. Due to the inductive effect of (CH3)3CO-three methyl groups, it is more basic and active than other potassium alkoxides, so it is a good catalyst. In addition, as a strong base, potassium tert-butoxide is widely used in chemical, pharmaceutical, pesticide and other organic synthesis, such as transesterification, condensation, strong rearrangement, polymerization, ring opening and the production of heavy metal orthoesters. It can be used to catalyze Michael addition reaction, Pinacol rearrangement reaction and Ramberg-BacChemicalbookklund rearrangement reaction; potassium tert-butoxide is used as a condensing agent and can be used to catalyze Darzens condensation reaction, Stobbe condensation reaction; it is also a traditional generation of dihalogenated carbene The most efficient base for the alkoxide-haloform reaction. Therefore, potassium tert-butoxide is more and more favored by chemical, pharmaceutical, pesticide and other industries. Potassium tert-butoxide is so widely used, so there is a large demand for high-purity potassium tert-butoxide at home and abroad. But because its production cost is higher than other alkali metal alkoxides, the production technology needs to be perfected, so the in-depth study of potassium tert-butoxide is particularly important.
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